How to add custom headers to the builtin OAuth token request?

It seems like the API you are hitting might not be following OAuth 2.0 norms. I don’t think there is a way to add the header to the built-in mechanism, but you can check out this article to add a pre-request script to your collection that will effectively do the same thing. Of course you will have to add the header into the request you are building, but that’s not too bad.